Researchers announce discovery in fundamental physics

When the transistor was invented in 1947 at Bell Labs, few could have foreseen the future impact of the device. This fundamental development in science and engineering was critical to the invention of handheld radios, led to modern computing, and enabled technologies such as the smartphone. This is one of the values of basic research. In a similar fashion, a branch of fundamental physics research, the study of so-called correlated electrons, focuses on interactions between the electrons in metals. The key to understanding these interactions and the unique properties they produce—information that could lead to the development of novel materials and technologies—is to experimentally verify their presence and physically probe the interactions at microscopic scales. To this end, Caltech's Thomas F. Rosenbaum and colleagues at the University of Chicago and the Argonne National Laboratory recently used a synchrotron X-ray source to investigate the existence of instabilities in the arrangement of the electrons in metals as a function of both temperature and pressure, and to pinpoint, for the first time, how those instabilities arise. Rosenbaum, professor of physics and holder of the Sonja and William Davidow Presidential Chair, is the corresponding author on the paper that was published on July 27, 2015, in the journal ("Itinerant density wave instabilities at classical and quantum critical points"). niobium diselenide One of the metallic samples studied, niobium diselenide, is seen here–the square in the center–as prepared for an X-ray diffraction experiment. (Image: University of Chicago/Argonne National Laboratory) "We spent over 10 years developing the instrumentation to perform these studies," says Yejun Feng of Argonne National Laboratory, a coauthor of the paper. "We now have a very unique capability that's due to the long-term relationship between Dr. Rosenbaum and the facilities at the Argonne National Laboratory." Within atoms, electrons are organized into orbital shells and subshells. Although they are often depicted as physical entities, orbitals actually represent probability distributions—regions of space where electrons have a certain likelihood of being found in a particular element at a particular energy. The characteristic electron configuration of a given element explains that element's peculiar properties. The work in correlated electrons looks at a subset of electrons. Metals, as an example, have an unfilled outermost orbital and electrons are free to move from atom to atom. Thus, metals are good electrical conductors. When metal atoms are tightly packed into lattices (or crystals) these electrons mingle together into a "sea" of electrons. The metallic element mercury is liquid at room temperature, in part due to its electron configuration, and shows very little resistance to electric current due to its electron configuration. At 4 degrees above absolute zero (just barely above -460 degrees Fahrenheit), mercury's electron arrangement and other properties create communal electrons that show no resistance to electric current, a state known as superconductivity. Mercury's superconductivity and similar phenomena are due to the existence of many pairs of correlated electrons. In superconducting states, correlated electrons pair to form an elastic, collective state through an excitation in the crystal lattice known as a phonon (specifically, a periodic, collective excitation of the atoms). The electrons are then able to move cooperatively in the elastic state through a material without energy loss. Electrons in crystals can interact in many ways with the periodic structure of the underlying atoms. Sometimes the electrons modulate themselves periodically in space. The question then arises as to whether this "charge order" derives from the interactions of the electrons with the atoms, a theory first proposed more than 60 years ago, or solely from interactions among the sea of electrons themselves. This question was the focus of the Nature Physics study. Electrons also behave as microscopic magnets and can demonstrate "spin order," which raises similar questions about the origin of the local magnetism. To see where the charge order arises, the researchers turned to the Advanced Photon Source at Argonne. The Photon Source is a synchrotron (a relative of the cyclotron, commonly known as an "atom-smasher"). These machines generate intense X-ray beams that can be used for X-ray diffraction studies. In X-ray diffraction, the patterns of scattered X-rays are used to provide information about repeating structures with wavelengths at the atomic scale. diamond anvil cell, a pressure vessel This cutaway schematic shows the diamond anvil cell, a pressure vessel in which the experiments were conducted. The target material is situated between two diamonds, represented here in blue. For this study, a diamond anvil generated pressures to 100,000 times sea level. (Image: University of Chicago/Argonne National Laboratory) In the experiment, the researchers used the X-ray beams to investigate charge-order effects in two metals, chromium and niobium diselenide, at pressures ranging from 0 (a vacuum) to 100 kilobar (100,000 times normal atmospheric pressure) and at temperatures ranging from 3 to 300 K (or -454 to 80 degrees Fahrenheit). Niobium diselenide was selected because it has a high degree of charge order, while chromium, in contrast, has a high degree of spin order. The researchers found that there is a simple correlation between pressure and how the communal electrons organize themselves within the crystal. Materials with completely different types of crystal structures all behave similarly. "These sorts of charge- and spin-order phenomena have been known for a long time, but their underlying mechanisms have not been understood until now," says Rosenbaum. Paper coauthors Jasper van Wezel, formerly of Argonne National Laboratory and presently of the Institute for Theoretical Physics at the University of Amsterdam, and Peter Littlewood, a professor at the University of Chicago and the director of Argonne National Laboratory, helped to provide a new theoretical perspective to explain the experimental results. Rosenbaum and colleagues point out that there are no immediate practical applications of the results. However, Rosenbaum notes, "This work should have applicability to new materials as well as to the kind of interactions that are useful to create magnetic states that are often the antecedents of superconductors," says Rosenbaum. "The attraction of this sort of research is to ask fundamental questions that are ubiquitous in nature," says Rosenbaum. "I think it is very much a Caltech tradition to try to develop new tools that can interrogate materials in ways that illuminate the fundamental aspects of the problem." He adds, "There is real power in being able to have general microscopic insights to develop the most powerful breakthroughs."
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New research could help build computers from DNA

New research from the University of East Anglia could one day help build computers from DNA. Scientists have found a way to 'switch' the structure of DNA using copper salts and EDTA (Ethylenediaminetetraacetic acid) - an agent commonly found in shampoo and other household products. It was previously known that the structure of a piece of DNA could be changed using acid, which causes it to fold up into what is known as an 'i-motif'. But new research published today in the journal ("Reversible DNA i-motif to hairpin switching induced by copper (ii) cations") reveals that the structure can be switched a second time into a hair-pin structure using positively-charged copper (copper cations). This change can also be reversed using EDTA. The applications for this discovery include nanotechnology - where DNA is used to make tiny machines, and in DNA-based computing - where computers are built from DNA rather than silicon. It could also be used for detecting the presence of copper cations, which are highly toxic to fish and other aquatic organisms, in water. Lead researcher Dr Zoë Waller, from UEA's school of Pharmacy, said: "Our research shows how the structure of our genetic material - DNA - can be changed and used in a way we didn't realise. "A single switch was possible before - but we show for the first time how the structure can be switched twice. "A potential application of this finding could be to create logic gates for DNA based computing. Logic gates are an elementary building block of digital circuits - used in computers and other electronic equipment. They are traditionally made using diodes or transistors which act as electronic switches. "This research expands how DNA could be used as a switching mechanism for a logic gate in DNA-based computing or in nano-technology."
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First demonstration of matter wave technique that could cool molecules

Researchers from the University of Southampton have demonstrated for the first time a new laser cooling method, based upon the interference of matter waves, that could be used to cool molecules. Our ability to produce samples of ultra-cold atoms has revolutionised experimental atomic physics, giving us devices from atomic clocks (the core of GPS) and enabling a range of quantum devices, including the possibility of a quantum computer. However, the current technique of cooling atoms down from room temperature to the ultra-cold regime using optical molasses (the preferential scattering of laser photons from a particle in motion which leads to slowing) is limited to atoms with favourable electronic structure. As a result, only a small fraction of atomic elements, along with a select few diatomic molecules, have been cooled in this manner. Writing in ("Interferometric Laser Cooling of Atomic Rubidium"), the research team at Southampton has provided the first proof-of-principle demonstration of a new laser cooling technique, based on a proposal by Martin Weitz and Nobel laureate Ted Hänsch in 2000, which is in principle applicable to atoms and molecules as yet untamed by conventional laser cooling. Laser Cooling Technique This is an end-on view of the vacuum chamber, showing ion pump, which maintains the high vacuum, to the left, and the photomultiplier tube and light collection lenses to the right. (Image: University of Southampton) Using the new approach, which harnesses the quantum interference of matter waves, the team was able to cool a sample of already-cold Rubidium down close to the fundamental temperature limit of laser cooling. The cooling technique is based on matter wave interferometry, in which an atom (the matter wave) is placed into a superposition of states by a laser pulse. The atom travels simultaneously along two paths, which interfere at a later time, and the impulse imparted to the atom depends on the difference between these paths. The same phenomenon can be used to engineer an extremely sensitive metrological device. Fundamentally, the impulse depends upon how the difference in energy along the two paths compares with the energy of the laser photons, where the atom's energy is formed of potential (internal electron configuration) and kinetic (external motion) parts. The clever trick behind Weitz and Hänsch's scheme is to make the laser interact with the atoms in such a manner as to remove the dependence on the potential energy, and thus the internal electronic structure, leaving the interference based solely on the kinetic energy of the particle. The team at Southampton has demonstrated the principle of using matter wave interference to cool atoms. Their results are a significant step toward decoupling the cooling mechanism from the internal electronic structure - the 'Holy Grail' of general molecular laser cooling. Dr Alex Dunning, from Physics and Astronomy at the University of Southampton and lead author of the study, said: "There is a great push to extend ultra-cold physics to the rest of the periodic table to explore a greater wealth of fundamental processes and develop new technologies and we hope that our demonstration will help. "While other cooling techniques can be effective they are limited to certain species and often require a multitude of lasers. Our technique, should we succeed in extending it to Weitz and Hänsch's complete scheme, would be sort of a catch-all; progress so far in cooling molecules tends to use the details of specific molecules, rather than being something general; that's why this is exciting, even though our actual experiment just uses atoms." Group leader, Dr Tim Freegarde, said: "These beautiful results have demonstrated that the method is feasible and can result in colder atoms than conventional Doppler cooling. To move on to other atoms and molecules will require more powerful lasers with shorter pulses, of the type used in coherent control chemistry, so the future of this method is very promising."
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